Modulating the assembly of organic dye molecules on titania nanocrystals via alkyl chain elongation for efficient mesoscopic cobalt solar cells.
نویسندگان
چکیده
Through elongating the end or side alkyl chains of dye molecules, we decorate anatase nanocrystals with a thicker organic assembly featuring a smaller tilt angle of the D-π-A backbone with respect to the surface normal, which retards the interfacial charge recombination and confers a higher photovoltage output on mesoscopic cobalt solar cells displaying an over 10% power conversion efficiency at the AM1.5G conditions.
منابع مشابه
Fabrication of Dye-Sensitized Solar Cells Using Native and Non-Native Nanocrystals in Ferritin as the Dye
Recent studies have demonstrated the potential of different nanocrystals synthesized in ferritin to act as light harvesters for high-efficiency solar cells. This study investigates the possibility of using these nanocrystals as alternative dyes for dye-sensitized solar cells. Four different dye-sensitized solar cells were successfully fabricated using iron, cobalt, manganese, and lead-sulfide n...
متن کاملThe DFT chemical investigations of optoelectronic and photovoltaic properties of short-chain conjugated molecules
The research in the short-chain organic -conjugated molecules has become one of the most interesting topics in the fields of chemistry. These compounds have become the most promising materials for the optoelectronic device technology. The use of low band gap materials is a viable method for better harvesting of the solar spectrum and increasing its efficiency. The control of the band gap of th...
متن کاملTitania nanobundle networks as dye-sensitized solar cell photoanodes.
Quasi-one-dimensional (1D) titania nanobundles were synthesized via a hydrothermal method and used to print random network nanostructured films. These films are shown to be ideally suited for application as photoanodes in dye-sensitized solar cells (DSCs) as they have a higher porosity compared to the traditional 1D nanostructured TiO2 materials. Devices constructed using the N719 dye and iodid...
متن کاملInsights into the limitations of solar cells sensitized with ruthenium dyes revealed in time-resolved spectroscopy studies.
The substitution of iodide electrolytes with cobalt ones has led to the current champion laboratory efficiencies for dye-sensitized solar cells (DSSCs). However, unlike with organic dyes, this strategy does not work with classical ruthenium dyes. Therefore, we compare DSSCs sensitized with a popular Ru dye (N719) using both types of electrolytes by exploring the electron dynamics occurring from...
متن کاملAcid azo dyes for efficient molecular photovoltaic: study of dye-sensitized solar cells performance
In this paper we sensitized three free-metal azo days Dye 1, Dye 2 and Dye 3 based on 1,8-naphthalimide with n-propyl as the electron donor group. We used sulfonic acid and hydroxyl substituents as the electron acceptor anchoring group in synthesized dyes. The proposed dyes were sensitized from acenaphthene as the starting material by standard reactions and characterized by different techniques...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Physical chemistry chemical physics : PCCP
دوره 14 23 شماره
صفحات -
تاریخ انتشار 2012